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      專家信息 科學(xué)研究 論文專著

      徐 正 男 教授 博士生導(dǎo)師。1962年畢業(yè)于南京大學(xué)化學(xué)系,1966年研究生畢業(yè)于中科院大連化學(xué)物理研究所。研究生期間從事高溫快速反應(yīng)動力學(xué)和化學(xué)激光研究;1968-1980年圍繞著二機(jī)部的任務(wù),開展新材料研制,解決了核材料的存貯問題,受到國防科委嘉獎和全國科學(xué)大會獎;1981年至今從事配位化學(xué)、納米化學(xué)、富勒烯化學(xué)的基礎(chǔ)研究。作為訪問教授曾多次去加拿大、意大利和德國進(jìn)行合作研究:1988-1990年 Guelph 大學(xué)和Concordia大學(xué)、1993年、1997年Guelph大學(xué),1999年Western Ontario大學(xué),2009年德國萊比錫大學(xué)、Max Planck界面和膠體研究所、意大利帕瑪大學(xué)等。曾承擔(dān)國家自然科學(xué)基金會重點(diǎn)項(xiàng)目,重大項(xiàng)目子項(xiàng)目,參與重大項(xiàng)目研究工作,主持江蘇省自然科學(xué)基金會重點(diǎn)項(xiàng)目的研究?蒲谐晒@國家自然科學(xué)三等獎,國家教委科技進(jìn)步一等獎和二等獎,2004教育部提名國家科學(xué)技術(shù)獎自然科學(xué)一等獎。發(fā)表科學(xué)論文300多篇, 6篇論文被選為熱點(diǎn)論文。論文被他引2000多次。獲授權(quán)專利7項(xiàng),出版專著一部。指導(dǎo)的一位研究生的博士論文入選全國優(yōu)秀博士論文。主要成就如下:

      一. 納米化學(xué)

      對納米晶可控合成和有序組裝進(jìn)行了系統(tǒng)的研究,建立了 “固液相合成方法”,實(shí)現(xiàn)了金屬納米粒子的大小可控,得到了不同尺度的納米晶和二維、三維超晶格。調(diào)控反應(yīng)的動力學(xué)和熱力學(xué)控制區(qū),實(shí)現(xiàn)納米粒子相結(jié)構(gòu)的調(diào)控。與“熱注入法” 相比,該方法不需用昂貴和有毒的有機(jī)金屬化合物,僅用價(jià)廉的無機(jī)鹽固體。建立了“智能” 膠體體系實(shí)現(xiàn)了溶液中半導(dǎo)體納米晶的一維外延生長。不需先制備晶種,體系會自動調(diào)節(jié)晶種和外延物種生成的時(shí)間,并產(chǎn)生與外延物種匹配的晶面,以調(diào)控外延半導(dǎo)體的相結(jié)構(gòu)。他們在限制空間內(nèi)構(gòu)筑了聚合物納米粒子的有序陣列,論文被選為Hot paper。

      把化學(xué)上不同的物種組合成一個(gè)區(qū)域組分可分的納米粒子是開發(fā)新功能材料的有效途徑, 因?yàn)楫愘|(zhì)界面間的強(qiáng)作用會產(chǎn)生新穎的性質(zhì)。軸向異質(zhì)復(fù)合結(jié)構(gòu)的構(gòu)筑較為困難,通常先制備納米線,后在納米線上外延生長第二種物種。他們則采用相反的方法,先制備殼,然后在殼內(nèi)構(gòu)筑第二種物種,構(gòu)成軸向異質(zhì)核殼結(jié)構(gòu)。建立了二級模板法,構(gòu)筑了一系列軸向異質(zhì)復(fù)合結(jié)構(gòu)有序陣列,把納米粒子的可控合成和有序組裝在一步中完成。研究了它們的微結(jié)構(gòu)、磁性和場發(fā)射性能等,與國際同類工作相比,具有金屬納米線連續(xù)完整、納米管填充率高等優(yōu)點(diǎn),處于國際先進(jìn)行列。

      聚合物/金屬軸向異質(zhì)復(fù)合結(jié)構(gòu)有效地保護(hù)了金屬納米線免受大氣的侵蝕,使納米結(jié)構(gòu)性能穩(wěn)定。論文已被他引一百多次。Niu 和 Chen 等對此工作的評價(jià)為:“用導(dǎo)電聚合物包覆的具有光、電、磁特性的無機(jī)納米棒結(jié)構(gòu)提供了一個(gè)令人振奮的體系,此體系可用來探索設(shè)計(jì)功能器件的可能性,因?yàn)榧{米同軸核殼結(jié)構(gòu)常常顯示出與單純的核和殼不一樣的物理和化學(xué)性質(zhì)!苯饘貱o和Ni納米管有序陣列的論文已被他引132次。第三世界科學(xué)院院長Rao在他的論文中詳細(xì)介紹了這項(xiàng)工作,并指出: “這是迄今為止已合成出的少數(shù)幾種金屬納米管之一! Dai 等指出:“徐等制備了高度有序的磁性Ni納米管陣列,長達(dá)35 μm,納米管具有增強(qiáng)的矯頑力,有可能在信息存儲等領(lǐng)域取得應(yīng)用” ;用溶膠-凝膠法構(gòu)筑了一系列金屬氧化物 (硫化物) /金屬軸向復(fù)合結(jié)構(gòu)有序陣列,金屬納米線有利于半導(dǎo)體光激發(fā)電子的存貯,改善了半導(dǎo)體的光電性能;用一步法構(gòu)筑了碳納米管/ZnS和CdS單晶納米線軸向異質(zhì)復(fù)合結(jié)構(gòu),長達(dá)十幾微米。在碳納米管中組裝Ni納米管構(gòu)成新穎的管中管結(jié)構(gòu)有序陣列,論文被該雜志選為Top Ten Most Accessed Article;他們在碳納米管內(nèi)組裝了長達(dá)50 μm的金屬納米線。填充率幾乎達(dá)100%。國際納米網(wǎng)站 nanotechweb.org 詳細(xì)介紹了這項(xiàng)工作,并指出:“南京大學(xué)的研究工作者已經(jīng)用二級模板法在碳納米管中填裝了金屬Co和Ni,該技術(shù)可用于制造納電子器件、高密度磁記憶器件、電化學(xué)能量儲存和傳感器等”;Jin的評價(jià)為:“將金屬納米粒子填入碳管后將會改變碳管的電子結(jié)構(gòu),因此通過改變金屬納米粒子的大小和濃度,能夠調(diào)控碳納米管的電子性質(zhì)。這類新穎的復(fù)合結(jié)構(gòu)不僅對于研究碳管和金屬粒子之間的相互作用具有重要的學(xué)術(shù)意義,而且對于催化、電、磁器件等應(yīng)用也十分重要”;系統(tǒng)研究了乳液,微乳液和多重乳液反應(yīng)體系的物理和化學(xué)性質(zhì),在液相中構(gòu)筑了磁性金屬亞微米和納米空心球,超結(jié)構(gòu)顯示出新穎的磁性質(zhì),兩篇論文均被選為 Top Ten Most Accessed Articles,還被 “Small” 雜志作為 highlights 論文介紹;發(fā)現(xiàn) ZnO 納米管有序陣列具有優(yōu)良的場發(fā)射性能,論文被選為Hot paper;用建立的固液相反應(yīng)路線,成功地構(gòu)筑了過渡金屬氧化物,稀土氧化物的單晶納米帶;對納米粒子的催化作用進(jìn)行了深入研究,發(fā)現(xiàn)了一例非金屬催化劑,該催化劑對硝基苯衍生物催化加氫制苯胺衍生物有極高的活性和選擇性;用小分子組裝得到了智能有機(jī)凝膠和有機(jī)超分子微管,凝膠對pH值高度敏感,可用pH可逆地調(diào)控溶膠/凝膠的轉(zhuǎn)變和粘彈力。這些工作都富有創(chuàng)新性。

      二.富勒烯化學(xué)和物理

      系統(tǒng)地研究了富勒烯的化學(xué)反應(yīng)。建立了選擇性合成C60、C70負(fù)離子水溶液和水溶膠的有效方法,為富勒烯在生物體中的應(yīng)用和構(gòu)筑納米結(jié)構(gòu)創(chuàng)造了條件;用Sol-gel法構(gòu)筑了C60和C70 納米管(線)有序陣列,進(jìn)而構(gòu)筑了C60和C70納米管/金屬Ni納米線軸向異質(zhì)復(fù)合結(jié)構(gòu)有序陣列。受到了國內(nèi)外同行的廣泛關(guān)注。Scott等采用了此選擇性還原方法,成功地在大量稠環(huán)芳烴混合物中檢測到了微量的C60,避免了繁復(fù)的分離和提純,證明了C60分子全合成的成功。朱道本教授等的評價(jià)為:“南京大學(xué)對C60、C70的還原反應(yīng)進(jìn)行了系統(tǒng)的研究,發(fā)現(xiàn)在酸性條件下,用化學(xué)還原生成富勒烯氫化物,但在堿性條件下則生成富勒烯負(fù)離子。文獻(xiàn)報(bào)道富勒烯負(fù)離子對水敏感,而在南京大學(xué)的實(shí)驗(yàn)室中發(fā)現(xiàn),C60n-、C70n-在無氧存在時(shí)對水并不敏感。更有意義的是,在國際上首次發(fā)現(xiàn)無需控制還原劑的化學(xué)計(jì)量,只要改變?nèi)軇,就能定量生成C60- 離子的水溶液!

      三.金屬配合物的研究:

      對稀土金屬配合物進(jìn)行了系統(tǒng)研究,發(fā)現(xiàn)了一些新反應(yīng)和新方法工作被 Edelmann 等廣泛引用;開展了多核配合物的研究,較早合成出Mn11Cr單分子磁體(SMM)。Chakov等指出此合成方法是目前用Mn12前體合成SMM的兩條主要路線之一。

      科學(xué)研究:

      研究方向:

      1.納米化學(xué):大小、形狀和相結(jié)構(gòu)可控的納米粒子的制備;納米線、納米管及納米復(fù)合結(jié)構(gòu)有序陣列的制備、結(jié)構(gòu)和性質(zhì)

      2. 納米材料合成中的配位化學(xué)

      在研項(xiàng)目:

      重大研發(fā)計(jì)劃:形狀化納米晶的可控合成,組裝和形狀相關(guān)性質(zhì)的研究

      973項(xiàng)目子課題:半導(dǎo)體納米線結(jié)構(gòu)設(shè)計(jì),可控制備及機(jī)理

      合作研究:

      1. 加拿大 International Scientific Exchange Award 作為訪問教授赴加拿大 Guelph 大學(xué)和 Concordia 大學(xué)進(jìn)行二年合作

      2. 1993年7月和1997年8月受 Guelph 大學(xué)邀請作為訪問教授進(jìn)行短期合作科研

      3. 1999年7月受 Western Ontario 大學(xué) CenPhysics 的邀請,作短期合作科研

      4. 2008年10-11月受德國MPI膠體和界面研究所,Leipzig大學(xué),意大利 Parma 大學(xué)的邀請,作短期合作研究。

      科研獎勵(lì):

      獲全國科學(xué)大會獎(1978年)

      國防科委多次嘉獎,江蘇省科學(xué)大會獎(1978年)

      國家自然科學(xué)三等獎(1991年)

      國家教委科技進(jìn)步一等獎和二等獎(1990和1996)

      教育部提名國家科學(xué)技術(shù)獎自然科學(xué)獎一等獎(2004)

      多次受邀在學(xué)術(shù)會議上做大會報(bào)告,分會邀請報(bào)告

      發(fā)明專利:

      1. Y2O3 納米帶負(fù)載 Ag 催化劑及其合成方法和應(yīng)用

      2. 納米級氧化銀及其生產(chǎn)工藝

      3. 一種納米級金粉及其制備方法

      4. 鐵磁性碳納米管的合成方法

      5. 耐高溫?zé)Y(jié)金水及其生產(chǎn)方法

      6. 一種包含金屬納米線碳納米管的合成方法

      論文專著:

      1. M. Han, Z. Xu,* et al., “Controllable synthesis and magnetic properties of cubic and hexagonal phase nickel nanocrystals”, Adv. Mater., 2007, 19, 1096-1100.

      2. F. F. Tao, Z. Xu,* et al., “An easy way to construct an ordered array of nickel nanotubes: The triblock-copolymer-assisted hard-template method”, Adv. Mater., 2006, 18 (16), 2161.

      3. Q. Liu, Z. Xu,* et al., “Nanometer-sized nickel hollow spheres”, Adv. Mater., 2005, 17(16), 1995.

      4. J. C. Bao, Z. Xu,* et al., “Facial synthesis of hollow nickle submicrometer spheres”, Adv. Mater., 2003, 15(21), 1832-1835.

      5. J. C. Bao, Z. Xu,* et al., “A facile method for creating an array of metal-filled carbon nanotubes”, Adv. Mater., 2002, 14(20), 1483-1486.

      6. J. C. Bao, Z. Xu,* et al., “An array of concentric composite nanostructures of zirconia nanotubules/cobalt nanawires, preparation and magnetic properties”, Adv. Mater., 2002, 14(1), 44-47.

      7. J. C. Bao, Z. Xu,* et al., “Template synthesis of an array of nickel nanotubles and Its magnetic behavior”, Adv. Mater., 2001, 13(21), 1631-1633.

      8. H. Q. Cao, Z. Xu,* et al., “Template synthesis of an array of cobalt nanowires encapsulated with polyaniline nanotubules and its magnetic behavior”, Adv. Mater., 2001, 13(2), 121-123.

      9. H. Q. Cao, Z. Xu,* et al., “Sol-gel template synthesis of array of single crystal CdS nanowires in porous alumina template”, Adv. Mater., 2001, 13(18), 1393-1394.

      10. F. F. Tao, Z. Xu,* et al., “Concentric sub-micrometer-sized cables composed of Ni nanowires and sub-micrometer-sized fullerene tubes”, Adv. Func. Mater., 2007, 17, 1124.

      11. N. Shi, Z. Xu,* et al., “A smart supramolecular hydrogel exhibiting pH-modulated viscoelastic properties”, Adv. Func. Mater., 2007, 17, 1837.

      12. M. Han, Z. Xu,* et al., “Large-scale synthesis of single-crystalline RE2O3 (RE= Y, Dy, Ho, Er) nanobelts by a solid-liquid-phase chemical route”, Chem. Eur. J., 2008, 4, 1615.

      13. N. Shi, Z. Xu,* et al., “Self-assembly of two different hierarchical nanostructures on either side of an organic supramolecular film in one step”, Chem. Eur. J., 2008, 14(20), 6255-6259.

      14. Y. Jiang, Z. Xu,* et al., “Fabrication of monodisperse colloidal array with confinement effects”, Chem. Commun., 2006, 75-77.

      15. J. C. Bao, Z. Xu,* et al., “A novel nanostructure of nickel nanotubes encapsulated in carbon nanotubes”, Chem. Commun., 2003, 208-209.

      16. H. Q. Cao, Z. Xu,* et al., “Sol-gel synthesis of array of C70 nanowires in porous alumina template”, Chem. Commun., 2001, 541-542.

      17. A. H. Yuan, Z. Xu,* et al., “An unusual three-dimensional porous framework complex {[Cu(en)2[KCr(CN)6]]}∞ from a temperate self-assembly reaction”, Chem. Commun., 2000, 1297-1298.

      18. Z. Z. Wu, Z. Xu,* et al., “A new bonding mode of oximato ligand to a metal:synthesis and X-ray crystal structure of bis[acctone oximato bis(cyclopentadienyl) gadolinium] [(C5H5)2Gd(μ-2)-ONeMe2]]2” J. C. S. Chem. Commun., 1994, 813.

      19. Z. Wu, Z. Xu,* et al., “Dehydrogenation reaction of organolanthanide alkoxides and X-ray crystal structure of reaction product [(C5H5)2Yb(μ-OCH=C=CH2)]2”, J. C. S. Chem. Commun., 1993, 1494.

      20. X. Li, Z. Xu,* et al., “Two growth modes of metal oxide in the colloidal crystal template leading to theformation of two different macroporous materials”, Chem. Mater., 2007, 19, 5424.

      21. J. C. Bao, Z. Xu,* et al., “An array of concentric composite nanostructure of metal nanowires encapsulated in Zirconia nanotubes: prepartion, characterization and magnetic properties”, Chem. Mater., 2002, 14(11), 4709-4713.

      22. X. P. Shen, Z. Y. Jiang, Z. Xu,* et al., “One-step construction of ZnS/C and CdS/C one-dimensional core–shell nanostructures”, J. Mater. Chem., 2007, 17, 1326-1330.

      23. Q. F. Zhou, Z. Xu,* et al., “Shape-controlled synthesis of nanostructrured gold by a protection-reduction technique”, J. Mater. Chem., 2002, 12, 384-387.

      24. H. Q. Cao, Z. Xu,* et al., “Iron nanowires encapsulated in polyaniline nanotubules and its magnetic behavior”, J. Mater. Chem., 2001, 11(3), 958-960.

      25. H. Li, Z. Xu,* et al., “Template-free fabrication of fullerene (C60, C70) nanometer-sized hollow spheres under solvothermal conditions”, Carbon, 2008, 46(13), 1736-1740.

      26. M. Han, Z. Xu,* et al., “Hollow nickel microspheres covered with oriented carbon nanotubes and its magnetic property”, Carbon, 2006, 44 (2), 211-215.

      27. X. Li, Z. Xu,* et al., “Controllable fabrication, growth mechanisms, and photocatalytic properties of hematite hollow spindles”, J. Phys. Chem. C. 2009, 19, 2837-2845.

      28. M. Han, Z. Xu,* et al., “Synthesis, characterization, and physicochemical properties of well-coupled Y2O3 nanobelt-Ag nanocrystals nanocomposites,” J. Phys. Chem. C. 2008, 112(46), 17893-17898.

      29. C. Gao, Z. Xu,* et al., “Hierarchical construction of composite hollow structures of Co@CoO and their magnetic behavior”, J. Phys. Chem. C. 2008, 112(25), 9272-9277.

      30. C. Gao, Z. Xu,* et al., “Controllable fabrication of mesoporous MgO with various morphologies and their absorption performance for toxic pollutants in water,” Crystal Growth & Design, 2008, 8(10), 3785-3790.

      31. M. Guan, Z. Xu,* et al., “A host crystal for the Rare-earth ion dopants: synthesis of pure and Ln-doped urchinlike BiPO4 structure and its photoluminescence”, Crystal Growth & Design, 2008, 8(8), 2694-2697.

      32. F. Tao, Z. Xu,* et al., “Fabrication of nickel hydroxide microtubes with micro- and nano-scale composite structure and improving electrochemical performance”, Crystal Growth & Design, 2008, 8(7), 2157-2162.

      33. J. Sun, Z. Xu,* et al., “Selective synthesis of gold cuboid and decahedral nanoparticles regulated and controlled by Cu2+ ions”, Crystal Growth & Design, 2008, 8(3), 906-910.

      34. Y. Ni, Z. Xu,* et al., “Shape-controllable preparation of PbS crystals by a simple aqueous-phase route”, Crystal Growth & Design, 2004, 4, 759

      35. M. Guan, Z. Xu,* et al., “Facile preparation method for rare earth phosphate hollow spheres and their photo-luminescence properties”, Langmuir, 2008, 24(15), 8280-8283.

      36. J. C. Bao, Z. Xu,* et al., “Synthesis and magnetic behavior of array of nickel-filled carbon nanotubes”, Appl. Phys. Lett., 2002, 81(24), 4592-4594.

      37. H. Q. Cao, Z. Xu,* et al., “Array of polyaniline nanotubules filled with nickel nanowires and its magnetic behavior”, Appl. Phys. Lett., 2001, 78(11), 1592-1594.

      38. M. Y. Guan, Z. Xu,* et al., “A novel cobalt submicro-wire network and its magnetic properties”, Chemphyschem, 2007, 8, 2182.

      39. W. L. Zhang, Z. Xu,* et al., “Controllable synthesis of CoO nanosheets and their magnetic properties”, Chemphyschem, 2007, 8, 2091.

      40. M. Y. Guan, Z. Xu,* et al., “Synthesis and luminescence of CePO4 and CePO4: Tb hollow and core-shell microspheres composed of single-crystal nanorods”, Nanotechnology, 2007, 18, 415602.

      41. H. J. Liu , Z. Xu,* et al., “A facile template-free route for synthesis of hollow hexagonal ZnS nano- and submicro-spheres”, Nanotechnology, 2005, 16 (12), 2908-2912.

      42. X. P. Shen, Z. Xu,* et al., “Fabrication, characterization and field emission properties of large-scale uniform ZnO nanotube arrays”, Nanotechnology, 2005, 16(10), 2039-2043.

      43. Z. Y. Suo, X. W. Wei, Z. Xu,* “New charge transfer complexes from dicyanodihydrofullerene and metallocene”, J. C. S. Dalton Trans., 1998, 22, 3875.

      44. N. Shi, Z. Xu,* et al., “Uncommon hexagonal microtubule based gel from a simple trimesic amide”, New J. Chem., 2008, 32(11), 2011-2015.

      45. X. P. Shen, Z. Xu,* et al., “Crystal structure and magnetic behavior of a three-dimentional cyano-bridged assembly [CuL1]2[Cr(CN)6]ClO4•0.5H2O (L1=3, 10-dcpropyl-1, 3, 5, 8, 10, 12-hexaazacyclo-tetradecane)”, New J. Chem., 2004, 28 (8), 996-999.

      46. M. Li, Z. Xu,* X. Z. You, X. Y. Huang, “One step synthesis and some reactions of ethyl 2, 3-dimethyl-8-(Ethyl-2', 3'-dimethyl-4'-Carboxylate) pyrrolo [2, 1-a] isoquinoline-1-carboxylate”, J. C. S. Perkin Trans. I, 1994, 2787.

      47. X. W. Wei, Z. Y. Suo, Z. Xu,* “New chemical method for selective generation of C70n-(n=1, 2, 3) anion and formation and properties of an aqueous colloidal solution of C70”, J. C. S. Perkin. Trans. II, 1999, (1), 121-126.

      48. X. W. Wei, M. F. Wu, Z. Xu,* et al., “Selective solution-phase generation and oxidation reaction of C60n-(n=1, 2) and formation of an aqueous colloidal solution of C60 ”, J. C. S. Perkin Trans. II, 1997, 1389.

      49. Y. Wu, X. P. Shen, Z. Xu,* et al., “New double-1, 2-amide-bridged calix[4]arene by aminolysis of the calix[4]arene esters”, Tetrahedron Lett., 1999, 40, 5749-5752.

      50. M. F. Wu, X. W. Wei, L. Qi, Z. Xu,* “A new method for facile and selective generation of C60- and C602- in aqueous caustic/THF (or DMSO)” Tetrahedron Letters, 1996, 37(41), 7409.

      51. X. P. Shen, Z. Xu,* et al., “Single crystal structure and magnetic behavior of a molecule-based ferrimagnet Mn[Mn0.2Cr0.8(CN)6]4H2O”, Eur. J. Inorg. Chem., 2007, 12, 1698-1702.

      52. J. C. Bao, Z. Xu,*, et al., “Fabrication of cobalt nanostructures with different shapes in Alumina template”, Scripta Materialia, 2004, 50(1), 19-23.

      53. X. Li, Z. Xu,* et al., “3-D ordered macroporous cuprous oxide: fabrication, optical, and photoelectrochemical properties”, J. Coll. Inter. Sci., 2007, 308, 460.

      54. G. Yin, D. Xu, Z. Xu,* “Spectral behavior of cis-2’, 5’-dipyridinylpyrrolidino [3’, 4’: 1, 2][60] fullerene and its coordination complex with zinc porphyrin (ZnTPP)”, Chem. Phys. Lett., 2002, 365, 232-236.

      55. H. B. Liu, Z. Xu,* et al., “Photo-physical properties of the transition metal ions complexes of the calix[4]arene derivatives”, Chem. Phys. Lett., 2001, 350, 441-446.

      56. H. B. Liu, Y. Xu, B. Li, G. Yin, Z. Xu,* “A new highly selective calix[4]arene-based fluorescent probe for Ca2+”, Chem. Phys. Lett., 2001, 345(5-6), 395.

      57. Z. Y. Suo, Z. Xu,* et al., “Optical limiting performance of dicyanodihydrofullerene”, Chem. Phys. Lett., 2001, 342, 497-502.

      58. Z. Suo, Y. Zhang, J. Zhang, Z. Xu,* C. Li, Z. Bai, “Generation and characterization of C60(CN)2n-(n=1, 2, 3)”, Chem. Phys. Lett., 1999, 315, 321-326.

      59. X. Wei, Z. Suo, Z. Xu,* “New solution-phase method for the preparation of alkali-earth metal fulleride Ca(C60)2, Ba(C60)2: synthesis and characterization with ESR, UV-NIR, IR and Raman spectroscopy”, Chem. Phys. Lett., 1999, 310, 15-20.

      60. X. W. Wei, C. Hu, Z. Y. Suo, P. Wang, W. Zhang, Z. Xu,* “Solid state 13C NMR and optical nonlinearities study of C60 trimethylenediamine adducts”, Chem. Phys. Lett., 1999, 300, 385-391.

      61. M. Li, Z. Xu,* et al., “Photophysical properties of dodecaphenyl-porphyrins with different substitutes”, Chem Phys. Lett., 1998, 288, 459.

      62. X. W. Wei, Z. Xu,* “Alkali-metal fullerides MC60(THF)x (M=Li, Na, K): a new solution phase method for the preparation and characterization with EPR, UV-NIR and IR spectroscopy”, J. Organometal. Chem., 2000, 599(1), 69-73.

      63. Z. Z. Wu, Z. N. Huang, Z. Xu,* et al., “Synthesis and thermol stability of binuclearbiscyclopentadienyl lanthanide thiolates, X-ray crystal structure of [CP2Yb(μ-S CH2CH2CH3)2 ”, J. Organomet. Chem., 1996, 506, 25.

      64. X. G. Zhou, H. Z. Ma, Z. Z. Wu, X. Z. You, Z. Xu,* “Synthesis and structure of a new organolanthanide oxide complex, (CH3C5H4Yb4(μ-Cl)6(μ3-Cl)(μ4-O)(THF)3”, J. Organomet. Chem., 1995, 503, 11.

      65. Z. Z. Wu, Z. Xu,* X. Y. Huang, “Dehydrogenation of organolanthanide alkoxides and X-ray crystal structures of reaction product [(C5H5)Ln(μ-OMeC=CHCH3)]2, (Ln = Dy, Yb)”, J. Organomet. Chem., 1994, 483, 107.

      66. Z.-Z. Wu, Z. Xu,* et al., “Synnthesis and X-ray crystal structure of the cyclopentadienyl nitrito complex of ytterbium (C5H5)2Yb(NO2)THF”, J. Organomet. Chem., 1993, 455(1-2), 93.

      67. Q. Liu, Z. Xu,* et al., “Three-dimensional five-connected coordination polymer [M2(C3H2O4)2(H2O)2(μ2-hmt)]n with 4466 topologies”, J. Solid State Chem., 2004, 177, 4701-4705.

      68. N. Shi, Z. Xu,* et al., “Anions bonded on the supramolecular hydrogel surface as the growth center of biominerals”, Colloids and Surfaces, B: Biointerfaces, 2008, 66(1), 84-89.

      69. Q. Liu, Z. Xu* et al., “Three-dimensional five-connected coordination polymer [M2(C3H2O4)2(H2O)2(mu2-hmt)]n with 4466 topologies (M = Zn, Cu; hmt = hexamethylenetetramine)”, J. Solid. State. Chem., 2004, 177 (12), 4701-4705. 1.486

      70. C. Gao, Z. Xu,* et al., “Ordered arrays of magnetic metal nanotubes and nanowires encapsulated with carbon tubes”, J. Nanosci. Nanotechno., 2008, 8(9), 4494-4499.

      71. Q. Liu, Z. Xu,* et al., “Large-scale synthesis of single crystal silver nanowires by a sodium diphenylamine sulfonate reduction process”, J. Nanosci. Nanotechno., 2006, 6 (1), 231-234.

      72. J. He, Z. Xu,* et al., “Crystal hierarchically splitting in growth of BaWO4 in positive cat-anionic microemulsion”, J. Cryst. Growth, 2008, 310(21), 4581-4586.

      73. X. P. Shen, Z. Xu,* et al., “Construction and photoluminescence of In2O3 nanotube array by CVD-template method”, J. Cryst. Growth, 2005, 276(3-4), 471-477.

      74. Y. H. Ni, Z. Xu,* et al., “A novel aqueous-phase route to prepare flower-shaped PbS Micro crystals”, J. Cryst. Growth, 2004, 262, 399-402.

      75. X. P. Shen, Z. Xu,* et al., “Template-based CVD synthesis of ZnS nanotube arrays”, Chemical Vapor Deposition, 2005, 11 (5), 250-253.

      76. Q. Liu, Z. Xu,* et al., “Solution phase synthesis of CuO nanorods”, Mater. Chem. and Phys., 2006, 98 (2-3) 519-522.

      77. Q. Liu, Z. Xu,* et al., “High yield synthesis of PbS nanocubes using one-step solid-state reaction in the presence of an anionic surfactant”, Mater. Chem. and Phys., 2005, 89(2-3), 379-382.

      78. X. P. Shen, Z. Xu,* et al., “Synthesis, characterization and magnetic properties of Co3O4 nanotubes”, Appl. Phys. A-Mater. Sci. & Proc. 2008, 91, 47.

      79. Y. H. Ni, Z. Xu,* et al., “Self-assembly of CuS nanoparticles to solid, hollow, spherical, tubular structures in a simple aqueous-phase reaction”, Appl. Phys. A-Mater. Sci. & Proc. 2004, 79(8), 2007-2011.

      80. Y. H. Ni, Z. Xu,* et al., “Fabrication and characterization of hollow cuprous sulfide (Cu2-xS) microspheres by a simple template-free route”, Inorg. Chem. Comm., 2003, 6, 1406-1408.

      81. B. L. Li, Z. Xu,* et al., “Synthesis and structure of novel coordination polymer: polycatenated {[Mn(bipy)(azpy)2(NCS)2]•H2O}n”, Inorg. Chem. Comm., 2001, 4, 451-453.

      82. J. Z. Zou, Z. Xu,* et al., “Synthesis, Structure and magnetic properties of a new polymeric compounds containing manganese(II)-Pzdc (Pzdc: 2,3-pyrazinedicarboxylic acid)”, Polyhedron, 1999, 18, 1597-1512.

      83. J. Z. Zou, Q. Liu, Z. Xu,* et al, “A novel three dimension network Copper(II) comples {[(Cudien)2(Cudien•H2O)TCB](ClO4)2•H2O}n”, Polyhedron, 1998, 17(11-12),1863.

      84. M. X. Li, Z. Xu,* et al., “A novel hydroxo-bridged ferric bisubstituted keggin heteropolytungstate dimer: synthesis and crystal structure of (Me4N)10[Fe4(OH)4(PW10O37)2]H2O”, Polyhedron, 1998, 17(21), 3721.

      85. H. Xu, J.-Z. Zou, J.-Y. Li, Z. Xu*, X.-Z. You, G.-C. Guo, J.-S. Huang, “Crystal structure and magnetic properties of a new oxo-centred basic benzoic bridging mixed-valence trinuclear complex MnⅢCoⅢMnⅡO(PhCOO)6Py3”, Polyhedron, 1997, 16(8), 1377.

      86. H. Xu, J. Li, J. Zou, Z. Xu,* X. You, G. Guo, J. Huang, H. Zhuang, “Crystal structure and magnetic properties of a new oxo-centred basic benzoate bridging heterotrinuclear compound[Cr2MnO(PhCOO)6Py3][CrO3Cl]”, Polyhedron, 1997, 16(8), 1371.

      87. Z. Z. Wu, Z. N. Huang, Z. Xu,* et al., “Synthesis and structure of binuclear bis-cyclopentadienyl ytterbium n-propyl. thiolate [C5H5]2Yb- SCH2CH2CH3(CH3)2]”, Polyhedron, 1996, 15(19), 3427.

      88. J. Y. Li, H. Xu, Z. Xu,* et al., “Synthesis,molecular structure and magnetic properties of [Mn11CrO12(CH3CO2)16(H2O)4]4H2O with A s=8 Ground State”, Polyhydron, 1996, 15(19), 3325-3329.

      89. H. Xu, J. Li, J. Zou, Z. Xu,* “Crystal structure and magnetic properties of a new heterotrinuclear compound”, Polyhedron, 1996, 15(19), 3325.

      90. M. X. Li, Z. Xu,* et al., “Crystal structure and magnetic properties of [Mn4](OOCCH2CH2COO)2(2, 2'-bipy)8](ClO4)4•3H2O”, Polyhedron, 1996, 15(3), 535.

      91. Z. Z. Wu, Z. N. Huang, Z. Xu,* et al., “Synthesis and characterization of dinuclear organclanthanide alkoxides, X-ray crystal structure of [C5H5]2Yb(μ-O(CH2)4CH3)2 and [C5H5]2Yb(μ-OCH2 CH2CH3(CH3)2)”, Polyhedron, 1996, 15(1), 13.

      92. J. Li, J. Zou, M. Wu, Z. Xu,* et al., “Synthesis, crystal structure and magnetic properties of a oxo-bridged binuclear iron (III) compound [Fe(phen)2phCOO]]2OCl2•7H2O”, Polyhedron, 1995, 14, 3519.

      93. Z. Z. Wu, Z. Xu*, X. Z. You, et al., “Formation and crystal structures of (C5H5)3Sm•OC4H8 and (C5H5)3Dy•OC4H8”, Polyhedron, 1994, 13(3), 379.

      94. M. Li, Z. Xu,* X. Z. You, X.Y. Huang, “X-ray crystal structure, spectral and magnetic properties of a mixed ligand dinuclear complex [Cu(phen)(Sa)(ClO4)]2”, Polyhedron, 1994, 14(5), 639.

      95. X. G. Zhou, Z. Xu,* et al., “Synthesis and structure of monocydo-pentadienyl yttrium(Ⅲ) dichloride tris(tetrahydrofuranate)”, Polyhedron, 1994, 13(3), 375.

      96. H. Xu, J. Li, Z. Wu, J. Zou, Z. Xu,* et al., “Synthesis and X-ray crystal structure of mixed valent cobalt complex Co2Cl5(Py)5”, Polyhedron, 1993, 12(18), 2261.

      97. M. Li, Z. Xu* et al., “Crystal structure and mass spectra of a copper(I) complex with a chain arrangement: [μ-4, 4'-bipy-Cu(TTA)]2”, Polyhedron, 1993, 12(8), 921.

      98. Z.-Z. Wu, Z. Xu* et al., “Synthesis and crystal structure of monocyclo-pentadienyl holmium dichloride tris (tetrahydrofuran)”, Polyhedron, 1993, 12(7), 795.

      99. Z.-Z. Wu, Z. Xu* et al., “Crystal structure and magnetic property of dicyclopentadienylholmium chloride [(C5H5)2HoCl]2”, Polyhedron, 1993, 12(6), 677.

      100. Z. Wu, Z. Xu*, X. You, et al., “Synthesis and characterization of binuclear organolanthanide complexes involving cyclopentadienyl and n-propyloxide ligands. X-crystal structure of [(C5H5)2Yb(μ-OCH2CH2CH3)]2”, Polyhedron, 1992, 11, 2673.

      101. S. Gou, X. You, Z. Xu,* et al., “Study on the transition metal complexes of tridentate schiff base ligand containing S, N, and O atoms: synthesis, structure and properties of mononuclear metal complexes”, Polyhedron, 1991, 10, 488.

      102. S. Gou, X. You, Z. Xu,* et al., “Transition metal complexes of the Schiff bases derived from S-alkyldithiocarbazate with 2-pyridinecarboxaldehyde N-oxide III. Synthesis, properties and structure of nickel(II) complexes”, Polyhedron, 1991, 10, 2659.

      103. Z. Xu,* E. C. Alyea, et al., “Stuctural characterization of a thiosemicarbazone derived from 2-acetyl pyridine N-oxide and its dimeric copper(II) nitrate complex”, Polyhedron, 1991, 10, 1625.

      104. S. Gou, P. Zheng, Z. Xu,* et al., “Transition metal complexes of the Schiff bases drived from S-alkydithiocarbazate with 2-pyridine carbox-aldehyde N-oxide II. Synthesis, properties and structure of five coordinate copper(II) complexes”, Polyhedron, 1991, 10(12), 1363.

      105. S. Gou, Z. You, Z. Xu,* et al., “Preparation and crystal structure of deprotonated S-methyl-N-(prydine N-oxide-2- ylmethylidene) dithiocarbazate pyridine nickel(II) perchlorate [Ni(C8H8 N3OS2) (C5H5N) ]ClO4”, Polyhedron, 1991, 10(1), 37.

      106. E. C. Alyea, Z. Xu,* et al., “The structure of a copper(I)-schiff base complex[Cu N(CH2CH2N=CHC6H5)3Bph4”, Polyhedron, 1990, 9(5), 739.

      107. S. Gou, X. You, Z. Xu,* et al., “Transition metal complex of the Schiff base derived from S-alkyldithiocarbazate with 2-pyridine carboxaldehyde N-oxide I. synthesis, properties and structure of four coordinate copper(II)”, Polyhedron, 1990, 9, 2981.

      108. E. C. Alyea, Z. Xu,* “Some copper(I) and copper(II) complexes of two new potentially heptadentate tripodal Schiff base ligands”, Polyhedron, 1990, 9, 2463.

      109. M. Li, Z. Xu,* et al., “The coordination dimer from ZnTPP and M(m-PyOMP) (M = H2 or Cu): spectroscopic properties and crystal structure”, Inorg. Chim. Acta, 1997, 261, 211.

      110. M. Gu, T. B. Tang, Y. Wu, Z. Xu,* et al., “Order-disorder transition in P-tert-butylcalix[8]arene - C60 Complex(1:1)”, Phys. Lett. A., 1999, 263, 131-135.

      111. Y. H. Ni, Z. Xu,* et al., “Microwave-assisted template synthesis of an array CdS nanotubes”, Mater. Letter, 2004, 58(22-23), 2754-2756.

      112. Q. F. Zhou, Q. Wang, Z. Xu,* et al., “The preparation of potassium silver cyanide by air blast cyanidation of superfine silver powder”, Mater. Lett., 2003, 57(13-14), 1915-1918.

      113. H. J. Liu, Z. Xu*, et al., “Fablication of submicrom Cu2O hollow spheres in an O/W/O multiemulsion”, Colloids and Surfaces A: Physicochem. Eng. Aspects, 2004, 235, 79-82.

      114. X. P. Shen, Z. Xu,* et al., “Synthesis and aracterization of Bi2S3 faceted nanotube bundles”, Solid State Communications, 2006, 140(3-4), 116-119.

      115. X. P. Shen, Z. Xu,* et al., “Fabrication of well-aligned CdS nanotubes by CVD-template method”, Solid State Communications, 2005, 133(1), 19-22.

      116. A. D. Xia, Z. Xu,* et al., “Characteristics of heterojunction diode of C60/chloroindium phthalocyanine”, Solid State Communications, 1995, 95(10), 713.

      117. M. Li, J. Zou, Z. Xu,* X. You, “7, 8, 17, 18-Tetrabromo-5, 10, 15, 20- tetra phenylporphyrin and It’s metal derivatives photophysical properties and electronic structure”, Spectrochim. Acta Part A, 1997, 53, 2109.

      118. Q. Liu, Z. Xu,* et al., “Synthesis and sructure of a novel three-dimensional coordination polymer[Cd3(μ3-hmt)2(μ2-C4H2O4)2(H2O)6]SO4.4H2O with (3,4) Connected Topological motifs (hmt=hexamethylenetetramine)”, J. Mol. Struct. 2005, 733(1-3), 25-28.

      119. X. P. Shen, Z. Xu,* et al., “The first cyano-bridged heptanuclear Mn(Ⅲ)6Fe(Ⅲ)cluster: crystal structucture and magnetic properties”, J. Mol. Struct., 2003, 657(1-3), 325-331.

      120. B. L. Li, Z. Xu,* et al., “Synthesis and crystal structure of two cobalt complexes: [Co2(4,4/-azpy)5(H2O)6][ClO4]4.(H2O)10.(4,4/-azpy)4 with a novel two-dimensional large rectangle organic-inorganic hybrid network and one-dimensional chain complex {[Co(3,3/-azpy)(H2O)4][ClO4]2. [3,3/-azpy]3}n”, J. Mol. Struct., 2001, 597(No.1-3), 21-30.

      121. Q. Liu, Z. Xu,* et al., “Large-scale synthesis of single-crystalline CuO nanoplatelets by a hydrothermal process”, Mater. Res. Bull., 2006, 41 (4), 697-702.

      122. Y. H. Ni, Z. Xu,* et al., “Rapid fabrication and optical properties of zinc sulfide nanocrystallings in a heterogeneous system”, Mater. Res. Bull., 2004, 39(12), 1967-1972.

      123. N. Shi, Z. Xu,* et al., “Coordination driving self-assembly of gold nanoparticles and tetrapyridylporphine into hollow spheres”, Chem. Lett., 2005, 34(11), 1468-1469.

      124. X. P. Shen, Z. Xu,* et al., “An efficient template pathway to synthesis of ordered metal oxide nanotube arrays using metal acetylatetonates as single-source molecular precursors”, Chem. Lett., 2004, 33(9), 1128-1129.

      125. B. L. Li, Z. Xu,* et al., “The first mixed-valence CoII III intrilotriacetate and 4, 4’-azobispyridine two ligand compex: synthesis and structure characterization of[CoIICoIII(NTA)2(azpy)2(H2O)]n∙n[CoII2CoIII(NTA)2(azpy)4(H2O)6∙4nH2O] with a new open sidearm ladders structure”, Chem. Letter, 2001, 214.

      126. B. L. Li, Z. Xu,* et al., “Self-assembly of a novel infinite triple helices coordination polymer: polycatenated {[Co(bipy)(azpy)2(NCS)2].H2O}n via hydrogen-bonding interaction”, Chem. Lett., 2001, 9, 902-903.

      127. Y. Xu, B. L. Li, Z. Xu,* et al., “Liquid crystalline thiadiazole derivatives: new ferroeletric thiadiazole derivatives”, Liquid Crystals, 2002, 29(2), 199-202.

      128. P. Wang, Z. Xu*, et al., “Substituents effect on the nonlinear optical properties of C60 derivatives”, Optics Commun., 2001, 192, 387-391.

      129. H. Zhou, S. G. Yang, Z. Y. Suo, Z. Xu,* et al., “Preparation and magnetic properties of array of Ni nanowire”, Acta Phys. Sinica, 1999, 48 (12), 8111.

      130. H. B. Liu, B. L. Li, Z. Xu,* et al., “Two novel self-assemblies of the calyx[4]arene Derivertives and their structures”, J. Inclusion phenomena and macrocyclic chemistry, 2003, 45, 9-11.

      131. Q. Liu, Z. Xu,* et al., “Solvothermal synthesis of CoFe2O4 hollow spheres”, J. Mater. Sci. 2007, 42, 10113.

      132. Q. Liu, Z. Xu,* et al., “Synthesis of nearly monodispersive gold nanoparticles by a sodium diphenylamine sulfonate reduction process”, J. Mater. Sci., 2006, 41(12), 3657-3662.

      133. Q. F. Zhou, Z. Xu,* et al., “Preparation of nano-scale plate silver powders by visible light induced method”, J. Mater. Sci., 2004, 39, 2487.

      134. Q. Liu, B. L. Li, Z. Xu,* et al., “Synthesis, crystal structure and magnetic property of [Mn2(mal)2(H2O)2(μ2-hmt)]n: a novel three-dimensional network self-assembled by HMT”, J. Coord. Chem., 2003, 56(9), 771-777.

      135. Q. Liu, Z. Xu,* et al., “A New azide-bridged three-dimensional supermolecular magnanese(II) compound: synthesis, crystal structure and magnetic properties”, J. Coord. Chem., 2002, 55(9), 1021-1027.

      136. B. L. Li, Z. Xu,* et al., “Synthesis, structure and characterization of the cyano-bridged heteropolymer [Cu(tn2)2[Co(cn)6(ClO4)•2H2O] with a two-dimensional framework”, J. Coord. Chem., 2002, 55(10), 1191-1198.

      137. B. L. Li, Z. Xu,* et al., “Synthesis, characterization and crystal structure of a one-dimensional chain [Cu(2,2’-bipyridine)(4,4’azobispyridine)(H2O)][ClO4] with rhomibic channels”, J. Coord. Chem., 2002, 55(10), 1183-1189.

      138. J. Z. Zou, M. Li, Z. Xu,* et al., “A cyano bridging copper(I)-iron(III) binuclear complex (cutren)Fe(CN)5NO2•2H2O: crystal structure and magnetic properties”, J. Coord. Chem., 1998, 43, 273.

      139. J. Zou, Z. Xu,* X. Huang, W.-L. Zhang, X.-P. Shen, Y.-P. Yu, “Crystal structure and magnetic properties of heterotrinuclear complex, (Cutren)2Fe(CN)6•12H2O”, J. Coord. Chem., 1997, 42, 55.

      140. H. Xu, J. Zou, J. Li, Z. Xu,* X. You, G. Guo, J. Huang, “A new oxo-centred, mixed-alence heterotrinuclear complex, Mn(Ⅲ)Ni(Ⅲ)Mn(Ⅱ)O(PhCOO)6Py3 crystal structure and magnetic properties”, J. Coord. Chem., 1997, 42, 45.

      141. Z. Wu, Z. Xu*, X. You, et al., “Crystal structure of (cyclopentadienyl)- dichlorogadolinium(Ⅱ)-tri(Tetrahydrofuran)”, J. Coord. Chem., 1992, 26, 329.

      142. L. Qi, C. Chang, X. W. Wei, Z. Xu,* et al., “Electrospray ionization mass spectroscopy analysis of the netral fullerenes”, Acta. Chem. Sinica, 1997, 55, 498.

      143. M. Li, Z. Xu,* et al., “Syntheses and magnetic properties of Cu(II), Ni(II) complexes bridged by 4, 4'-bipyridine, pyrazine and imidazole”, Acta. Chim. Sinica., 1995, 53, 847.

      144. J. Z. Zou, Z. Xu,* et al., “Electronic structure of H2TPPBr4 and MTPPBr4 and crystal structure of Ni(TPPBr4))”, Acta Chim. Sinica, 1994, 52, 683.

      145. M. X. Li, Z. Xu*, “Synthesis, structure and magnetic properties of [M(TTA)2•μ-4, 4'-bipy]n”, Acta Chim. Sinica, 1994, 52, 174.

      146. S. H. Gou, Z. Xu,* et al., “Study on the tripodal transition metal complexes with ferrocenyl groups as arms”, Acta Chim. Sinica, 1992, 50, 1105.

      147. Z. Xu,* J. H. Lin, et al., “Synthesis and molecular structure of Co[(C2H5O)2PS2]2•2Py”, Acta Chim. Sinica, 1989, 47, 623.

      148. Z. Xu,* et al., “The study on thermodynamic properties of adduct formation between bis-(O, O'-dioctyldithiophosphato) nickel(II) and the primary alkanol by GLC method”, Acta Chim. Sinica, 1988, 46, 740.

      149. S. Han, Z. Xu,* et al., “Electron paramagnetic resonance study on Cu[(C6H11O)2PS2]2 complex single crystal”, Acta Chim. Sinica, 1988, 46, 302.

      150. Z. Xu,* X. You, et al., “The crystal structure of binuclear copper (II) complex [Cu2](C20H12ClN2O3)OCH3H2O of the bis-schiff base”, Acta Chim. Sinica, 1985, 43, 1039.

      151. X. P. Shen, Z. Xu,* et al., “Synthesis, crystal structures and magnetic properties of two cyano-bridged two-dimensional assemblies[Fe(salpn)]2[Fe(CN)5NO] and [Fe(sapn)2][Ni(CN)4]”, Tran. Met. Chem., 2004, 29, 100-106.

      152. Q. Liu, B. L. Li, Z.Xu,* “A novel three-dimensional coordination polymer [Cd2(C3H2O4)2(H2O)2(μ2-hmt)]n : synthesis and crystal structure”, Tran. Met. Chem., 2002, 27, 786-789.

      153. X. P. Shen, Z. Xu,* et al., “Crystal structure of a cyanide-bridged heptanuclear manganese(III)-chromium(III) complex with a ground state s=21/2”, Trans. Met. Chem., 2002, 27, 372-376.

      154. Q. Liu, B. L. Li, Z. Xu,* et al., “Synthesis and crystal structure of [Ag2(-hmt)(NO2)]n. A two-dimensional network with square cavties self-assembled by hmt”, Tran. Met. Chem., 2001, 26, 369-371.

      155. B. Li, Z. Xu*, Z. Cao, L. Zhu, K. Yu, “One dimensional chain copper complexes [Cu(dien)(btrz)(ClO4)2] and [Cu(en)2(btrz)(ClO4)2]”, Trans. Met. Chem., 1999, 24, 622-627.

      156. J. Z. Zou, Z. Xu,* et al., “Synthesis and magnetic properties of one dimensional linear chain structure cyano bridging complex(Cuteta•2H2O) [CutetaFe(CN)6]ClO4•H2O”, Trans. Met. Chem., 1998, 23, 477.

      157. J. Z. Zou, Z. Xu,* et al., “Crystal structure and magnetic properties of a new polymer (Cu)pzdcH)2•2H2O]n”, Trans. Met. Chem., 1998, 23(4), 481.

      158. J. Z. Zou, Z. Xu,* “Crystal structure and strong antiferromagnetic interaction of a terephalatebridged binuclear Copper(II) complex (Cudipn)2 (μ-TPHA)(ClO4)2(dipn:N(3-aminopropyl)-1,3-propanediamine)”, Trans. Met. Chem., 1998, 23(3), 305.

      159. Z. Wu, Z. Xu,* et al., “Synthesis and study on thermal stability of cyclopentadienyl (or Indenyl) early lanthanide complexes involving 8-quinolinolato and O-aminophenolato chelate ligands” Synth. React. Inorg. Met.-Org. Chem., 1993, 23(7), 1155.

      160. J. H. Lin, Z. Xu,* et al., “EPR study on single crystal of Bis-[O,O'-(2,2'-bisphenyl)dithiophosphato] copper(II) complex”, Chin. Sci. Bull., 1989, 6, 558.

      161. X. Zhou, Z. Wu, Z. Xu,* et al., “Thermodytic reactivity of Cp2HoCl and X-ray structure of the thermolysis product [(C5H3CH=CHCH2C=CHC5H4)2Ho2Cl2”, Chin. Sci. Bull., 1995, 40(7), 552.

      162. X. Z. You, Z. Xu,* et al., “Equilibrium constant of adductive reaction between Bis-(O,O'-Dicyclohexyldithiophosphato) Nickel(II) and benzylamine and crystal structure of adducts Ni[(C6H11O)2PS2]2•2NH2CH2C6H5”, Chin. Sci. Bull., 1992, 37(8), 657.

      163. Y. H. Ni, Z. Xu,* et al., “PbS crystals with clover-like structure: preparation, characterization, optical properties and influencing factor”, Cryst. Res. Technol., 2004, 39(3), 198-204.

      164. Y. Xu, Z. Zhu, Z. Xu,* “Liquid crystalline thiadiazole perivatives: thiadiazole derivatives containing pyriding ring as terminal group”, Chin. J. Chem., 2001, 19, 870-876.

      165. G. Yin, X. Mao, Z. Suo, Z. Xu,* “Synthesis and electronic properties of C60-carbazole adducts”, Chin. J. Chem., 2001, 19, 822-828.

      166. H. B. Liu, Z. Xu,* et al., “Crystal structure and luminescence of [Eu(TTA)3•DAF] •0.5C7H8 complex excited by visible light”, Chin. J. Chem., 2001, 19, 766-771.

      167. X. P. Shen, Z. Xu*, et al., “A new two dimensional cyano-bridged chromium (III)-Nickel (II) bimetallic assemly with stair-like layers”, Chinese J. Chem., 2001, 19(6), 627-629.

      168. Y. Wu, Z. Xu,* “Aminolysis reaction of calyx[4]arene esters and crystal structures and conformation behavior of calyx(4) arene amide”, Chin. J. Chem., 2000, 18(1), 94-103.

      169. M. Li, X. Chen, J. Zou, Z. Xu,* “A spectral study of single meso-(hydroxylthenyl) octamethylporphyrins”, Chin. J. Chem., 1996, 14(1), 20.

      170. M. Li, Z. Xu,* et al., “Synthesis, spectroscopic properties and tautomerism of mono-meso-substituted-octamethylporphyrins”, Chin. J. Chem., 1994, 12(3), 237.

      171. S. Gou, P. Zheng, Z. Xu,* et al., “Synthesis and structure of a new polynuclear complex with a monomer of (3, 4, 9, 10-dibenzo-1, 12-diaza-5, 8-diox-acyclopentadecane)copper(II) (μ-Cl)2] zine(II) chloride”, Chin. J. Chem., 1992, 10(3), 232.

      172. B. L. Li, Z. Xu,* et al., “Synthesis, structure and characterization of two-dimension network copper complexes [Cu3(nta)2(azpy)2(H2O)2]•6H2O”, Chin. J. Chem., 2002, 20, 187-190.

      173. Q. Liu, Z. Xu,* et al., “Diaquabis(hexamethylenetetsamine-N) bis(isothiocyanato) -manganese(Ⅱ) etraquabis(isothiocyanato) manganese(Ⅱ) dihydrate”, Acta Cryst. E, 2001, 57, m151-m153.

      174. B. L. Li, X. P. Shen, J. Z. Zou, Z. Xu,* et al., “A three-dimensional porous framework complex, poly[[bis(ethylenediamine)copper(II)] [potassium hexacyanocobalt(III)]]”, Acta Cryst. C, 2001, 57, 1242-1244. 0.719

      175. B. L. Li, X. W. Wei, Z. Xu,* “Synthesis and crystal structure of [Cu(TTA)2]2•C2H3N3CH2CH2 C2H3N3”, Acta. Cryst. C., 1999, 55, 165-167.

      176. W. Chen, J. Z. Zuo, Z. Xu,* et al., “A tetracarboxylatobenzene-bridged binuclear copper(II) complex”, Acta Cryst. C, 1996, 52(1), 43.

      177. D. L. Zhu, Y. P. Yu, Z. Xu,* et al., “Catena-poly[Bis(O, O')-diethyldithiophosphato-S' Zinc-μ-(4, 4,)-bipyridyl-N:N']”, Acta. Cryst. C., 1996, 52, 1963.

      178. X. G. Zhou, Z. Ma, X. Z. You, Z. Xu,* “Benzopyenone adduct of triscyclopentadienyl dysprosium”, Acta. Cryst. C., 1996, 52, 187.

      179. E. C. Alyea, G. Ferguson, Z. Xu,* “Hydrogen-bonded self-assembly of 2, 2', 2''-triamino triethylamine molybdrate, 4[N(CH2CH2NH3)2+]3•6[MoO4]2-•6H2O” Acta Cryst. C, 1995, 51, 353.

      180. J. Zou, Z. Xu*, M. Li, et al., “7, 8, 17, 18-Tetrabromo- 5, 10, 15, 20-tetra -phenylporphyrin”, Acta Cryst. C, 1995, 51, 760.

      181. G. Ferguson, E. C. Alyea, Z. Xu,* “The crystal structure of the copper tripodal schiff base complex, {Tris-[4-(2-thienyl)-3-aza-KN-butaenyl]amine-KN}Copper(I) Tetrafluoroborate”, Acta Cryst. C, 1994, 50, 16.

      182. M. Li, Z. Xu,* et al., “Binuclear copper(II) complex: bis[4, 4, 4-trifluoro-1-(2-thienyl)butane-1, 3-dionato-O, O']copper(II) bridged by 4, 4'-bipyridine”, Acta Cryst. C, 1994, 50. 1699.

      183. S. Gou, X. You, Z. Xu,* et al., “Structure of catena-poly {bis[1, 1, 1, -trifluorobutane -1, 3-dionato-K2]O, O'} copper-μ-(4, 4'- bipyridine)-KN,KN'}}”, Acta Cryst. C, 1991, 47, 2653.

      184. S. Gou, Z. You, Z. Xu,* et al., “Catena-poly {bis[1-(2-thienyl) -4, 4, 4-trifluorobutane -1, 3- butanedionato-K2] O, O'} copper-μ-(4, 4'-bipyridine) -KN:KN'} -N, N-dimethylformamide(1/2)”, Acta Cryst. C, 1991, 47, 1303.

      185. S. Liu, Z Xu,* et al., “Structure of a five-coordinated nickel complex: [Ni{(C2H5O)2PS2}2 P(C6H5)3]”, Acta Cryst. C, 1991, 47, 43.

      186. S. Gou, Z. You, Z. Xu,* et al., “Structure of 2,2'-[5-(2-Aminoethyl)-1-hydroxy-2,5,8-triazanon-3-en-1,9-diyl]bis(pyridine-N-oxid)nickel hexafluorophosphate hydrate: A novel tripodal nickel(II) complex with three inequivalent arms”, Acta Cryst. C, 1991, 47, 708.

      187. Z. Xu*, S. Gou, et al., “Structure of a five-coordinate copper(II) complex of (2,2'-bipyridine) [4,4,4- trifluoro-1- (2-thienyl) butane-1,3-dionato-O] [4,4,4-trifluoro-1-(2-thienyl) butane-1,3- dionato-O,O'] copper(II)”, Acta Cryst. C, 1991, 47, 81.

      188. E. C. Alyea, Z. Xu,* et al., “Structure of a copper(I) complex of a tripodal schiff base ligand, tris[4-(2-thienyl)-3-aza-butenyl]amine copper(I) triiodide chloroform solvate”, Acta Cryst. C, 1990, 46, 2347.

      189. J. Huang, Y. Yu, Z. Xu,* et al., “Structure of the adduct of bis(O,O'-dibutyldithiophosphato)nickel(II) with imidazole”, Acta Cryst. C, 1990, 46, 991.

      190. X. Z. You, J. Chen, Z. Xu,* et al., “Structure of hexakis (isopropylammonium) diformyloctamolybdate”, Acta Cryst. C, 1989, 45, 413.

      191. E. C. Alyea, Z. Xu,* et al., “Structure of a potentially heptadentate tripodal ligand tris[4-(2-thienyl)-3-aza-3-butenyl]amine”, Acta Cryst. C, 1989, 45, 1566.

      192. Q. F. Zhou, Z. Xu,* et al., “A novel shape-selection fabrication of nanostructured silver”, Science in China B, 2002, 45, 416-420.

      193. G. Yin, Z. Xu,* “Synthesis of water-soluble C60 derivatives and their scavenging free radical activity”, Science in China B, 2002, 45(1), 54-59.

      194. X. W. Wei, M. F. Wu, Z. Xu,* et al., “Addition reaction of buckminsterfullerene with amines and electrospray ionization mass spectrometry determination of reaction products”, Chem. J. Chin. Univ., 1996, 17, 1570.

      195. J.-C. Bao, X. Ni, Z. Xu,* et al., “Synthesis and magnetic exchange interaction of heterobinuclear Cu(II)-Co(II) complexes” Chem. J. Chin. Univ., 1994, 15(2), 178.

      196. M. X. Li, Z. Xu* et al., “Synthesis, crystal structure and properties of TAAB nickel adducts with axial N-base ligands”, Chem. J. Chin. Univ., 1993, 14(6), 745.

      197. Z. Z. Wu, Z. Xu,* et al., “Synthesis and studies on thermal stability of dicyclopentadienyl lanthanide 8-hydroxyquinolinolato complexes”, Chem. J. Chin. Univ., 1993, 14(1), 9.

      198. Y. P. Yu, Z. Xu,* et al., “Synthesis and crystal structure of the complex of bis[4, 4, 4-trifluoro-1-(2-thienyl)butanedione-1,3]copper(II) with diquinoline”, Chem. J. Chin. Univ., 1991, 12(2), 157.

      199. K. B. Yu, S. H. Gou, Z. Xu,* et al., “Crystal and molecular structure of copper (II) dimeric complex of S-methyl-β-N-(pyridine N-oxide-2-ylmethylidene) dithio- carbazate with Acetonitrile”, Chem. J. Chin. Univ., 1991, 12(7), 869.

      200. Y. P. Yu, Z. Xu,* et al., “Study on the thermodynamic properties of adduction reaction between Ni[(C8H17O)2PS2]2 and aldehydes by GLC method”, Chem. J. Chin. Univ. 1990, 11(5), 551.

      201. K. Yu, S. Gou, Z. Xu,* et al., “Crystal and molecular structure of copper (II) dimeric complex of S-methyl-N- (pyridine N-oxide-2- ylmethylidene) dithiocarbazate with acetonitrile”, Chem. J. Chin. Univ., 1990, 11(4), 262.

      202. S, Gou, X. You, Z. Xu,* et al., “Synthesis and magnetic properties of copper(II) complexes with pyridine N-oxide-2-ylmethylidene dithiocarbazate as ligands”, Chem. J. Chin. Univ., 1990, 11(4), 255.

      203. S. X. Liu, Z. Xu,* et al., “Determination of equilibrium constants for the adductive reaction of bis-(O, O'-Dicyclohexyl-dithiophosphato) Nickel (II) with pyridine and the crystal structure of Ni[(C6H11O)2PS2]2•2Py”, Chem. J. Chin. Univ., 1989, 10(12), 1225.

      204. Z. Xu,* et al., “Synthesis and crystal structure of tri-(O, O'- Diethyldithio phosphato) Cobalt (III)”, Chem. J. Chin. Univ., 1988, 9(5), 432.

      205. Y. P. Yu, Z. Xu,* et al., “Determination of thermodynamic parameters of adduct reaction of Ni[(C8H17O)2PS2]2 and (C2H5)3N by GLC Method”, Chem. J. Chin. Univ., 1988, 9(1), 9.

      206. H. Li, Z. Xu,* et al., “Self-assembly of gold nanoparticles monolayer film at water/oil interface”, Chin. J. Inorg. Chem., 2008, 24, 1664-1668.

      207. M. Han, Z. Xu,* et al., “Synthesis, characterization and electrochemical properties of multi-layered porous Co3O4 nanoparticle assemblies”, Chin. J. Inorg. Chem., 2008, 24, 797-802.

      208. D. M. Zhu, Z. Xu,* et al., “Preparation and characterization of inorganic-polymer-inorganic multicomponent core-shell nanocomposite material”, Chin. J. Inorg. Chem., 2007, 23, 2128.

      209. W. L. Zhang, Z. Xu,* et al., “Scheelite BaWO4 nanowire bundles: controllable synthesis and optical properties”, Chin. J. Inorg. Chem., 2007, 23, 1796.

      210. X. P. Shen, Z. Xu,* et al., “Hydrothermal synthesis of Sb2S3 nanorod ordered arrays”, Chin. J. Inorg. Chem., 2007, 23, 1561.

      211. T. M. Shang, Z. Xu,* et al., “A new photochromic film: Na2WO4-PAA-glycerol system”, Chin. J. Inorg. Chem., 2007, 23, 124.

      212. M. Han, Z. Xu,* et al., “Synthesis and optical properties of alpha-ZnS single crystalline nanowire bundles”, Chin. J. Inorg. Chem., 2006, 22, 1585-1590.

      213. X. W. Wei, Z. Xu,* et al., “Synthesis and photophysical properties of fullerene derivatives”, Fullerene nanotubes and carbon nanostructures, 2002, 10(2), 137-153.

      214. B. L. Li, Y. Xu, Y. J. Liu, Z. Xu,* “Synthesis, structure and magnetic properties of an interlock network frame of cobalt (II) coordination polymer {[Co(azpy)2(NCS)2]•1/4EtOH•1/2H2O}n ”, Chem. Res. Chin. Uni., 2001, 17(3), 237-242.

      215. S. W. Wang, X. W. Wei, L. Qi, Z. Xu,* “Synthesis and characterization of divalent organolanthanide-fullerene adducts Cp2LnC60(Ln=Yb,Sm):first example of insertion reaction involving cyclopentadienyl and fullerene”, Fullerene Sci. and Techn., 1998, 6(6), 1087.

      216. Z. Suo, X. Wei, Y. Mei, Z. Xu,* “Group transfer and dimerization processes of C60(CN)2 in atomspheric ionization conditions”, Fullerene Sci. and Techn., 2001, 9(2), 211-223.

      217. X. Wei, Z. Suo, Z. Xu,* “Syntheses and characterization of some organic dye buckminsterfulleride”, Fullerene Sci. and Technol., 1999, 7, 781-793.

      218. Y. Wu, Z. Xu,* et al., “A facile method of synthesis of calix(4)arene amide and the first example of a self-assembly calix(4)arene via van der waals interaction”, J. Inclusion Phenomena Chem., 2000, 36(4), 473-476.

      219. X. Z. You, H. W. Chen, Z. Xu,* “metal cluster chemistry”, Chemistry Bulletin, 1985, 9, 5.

      220. 徐 正,“化學(xué)反應(yīng)速率理導(dǎo)論” 江蘇科學(xué)技術(shù)出版社 1987, 江蘇南京, pp.643.

       

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